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"To leaven" means to make light; to raise. Leavening agents are responsible for the volume in most baked food products. They are responsible for expanding the air bubbles that have been mixed, creamed, kneaded or whipped into the batter. This results in a delicious recipe, with lots of volume--only as long as there are adequate air bubbles. Leaveners also contribute to a baked goods' taste, coloring and texture. 

Leavening agent; leavener:
1. A substance used to leaven a dough or batter; may be natural (ex. air or steam), chemical (ex. baking powder or baking soda) or biological (ex. yeast). 2. A type of food additive used to produce or stimulate production of carbon dioxide in baked goods to impart a light texture.

NOTE: Chemical leaveners must be stored in a cool, dry place and and only dry utensils are used when measuring from the can. Once moistened, baking soda has been activated and is no longer good. To Test if still ACTIVE:
Baking Soda Test: Add a couple tablespoons of white vinegar into a small cup, add 1 teaspoon of baking soda. If it froths, even a little, it's good.
Baking Powder Test: To check your baking powder to see if it still causes a leavening reaction, first stir the contents of the can to see if there is any lumps. This is an indication that the baking powder has picked up moisture, and started a reaction in the can.

You can place a teaspoon of baking powder in a glass of tepid water to see if it fizzes.

Check the code dates on the bottom of the can to make sure it is still in code. Baking powder has a usual useful life of 24 months from the date of manufacture.

Start your holiday or any large baking project with fresh boxes of baking soda and baking powder. I always do.

Ever wonder why that soufflé puffs up so high and then falls so fast?  Why does your quick-bread rise? Do you know your baking powder from your baking soda? Simply read on to learn how to get the best rise out of your baked goods!

When refrigerating or freezing batters or dough, the chemical leaveners in them, such as baking powder, baking soda and yeast will lose their potency in about 30 minutes!  So, it is best not to store them too long.

The basic leavening gases commonly found in baking recipes are air (called mechanical) from whipped eggs, or beating, stirring, creaming and kneading; water vapor or steam from liquids; carbon dioxide from chemical leaveners, baking soda and baking powder; and yeast, both packaged and from a starter (sourdough or sponge). In baking recipes, one or more leavening agents participate in the leavening process.  

However, chemical leaveners and yeast usually are not combined, but there are exceptions. Saltine crackers and pretzels undergo yeast fermentation, but the primary reason is to generate flavor and dough conditioning. The subsequent sheeting action removes much of the gas that is generated, and chemical leaveners are required to provide lift during baking. In some frozen or refrigerated doughs found in the grocery store, yeast and chemical leavenings complement each other.

CHEMICAL LEAVENERS: Baker's Ammonia, Baking Powder & Baking Soda. (How Chemical Leaveners Work).

QUESTION: If you don't use enough leavener in some recipes, your cake won't puff. But, if you use too much leavener, the cake still won't puff up. Why?

ANSWER: Because, says Shirley Corriher, a cookbook author, food chemist and advisor to baking911.com, when you use too much leavener the bubbles in the cake batter will get too big, run into each other, float to the top and pop! Then there aren't enough bubbles left to hold up the cake.

So, you can see why it's important when you are cooking to follow the ingredient list and instructions exactly and measure carefully.

BAKER'S AMMONIA (AMMONIUM CARBONATE): Don't confuse this with ordinary household ammonia, which is poisonous.  A type of baking powder, it yields a very light, airy product, but can impart an ammonia flavor to baked goods. It's best used in cookies, which are flat enough to allow all of the ammonia odor to dissipate during cooking. Northern Europeans still use it because it makes their springerle and gingerbread cookies very light and crisp. Look for it in German or Scandinavian markets, drug stores, baking supply stores, or a mail order catalogue. It comes either as lumps or powder. If it isn't powdered, crush it into a very fine powder with a mortar & pestle or a rolling pin.  

Baking Powder: fine white powder sold prepackaged Baking powder was not available until the 1860s in the United States.
bulletUsed in making quick-bread recipes, cakes, cookies and other related recipes.
bulletNeeds heat to be activated
bulletUsually mixed in with the dry ingredients
bulletIf too much is used, it will make foods taste bitter and peppery in taste

BAKING POWDER, DOUBLE ACTING: Baking powder is basically a blend of acid (most commonly calcium acid phosphate, sodium aluminum sulfate or cream of tartar) and baking soda (alkali - sodium bicarbonate), creating carbon dioxide bubbles when both moistened and heated. 

For one teaspoon SINGLE-ACTING baking powder: mix 1/2 teaspoon cream of tartar plus 1/4 teaspoon baking soda. Single-acting means that it will create gas quickly when moistened, so the batter must be cooked quickly or it will go flat. For double-acting baking powder, the kind commonly used in recipes and sold in grocery stores, there isn't any easy substitution. (There is not substitute for baking soda)

It is known as a double acting chemical leavener -- it begins release carbon dioxide as soon as it is moistened, and again when heated in the oven. (There are single acting baking powders, but are rarely used by home bakers). Always use double acting in recipes; it is virtually the only type available in grocery stores.

Baking powder does not need an acidic ingredient to release its leavening power, as baking soda does, because it contains its own; baking powder contains 30 percent baking soda (alkaline) and an acid, such as cream of tartar.

There are several different types of acids used in baking powder, each with a different pattern of producing gas bubbles, such as slow or fast, immediate or delayed. Most supermarket brands brands are double-acting, meaning it releases a portion of its gas in the cold batter/dough and quickly releases the remainder when heated in baking. Recipes using typical supermarket baking powder brands should be baked right after mixing because the acids they contain dissolve quickly. Some slow-release acids are only available to commercial manufacturers and restaurants, allowing batters to sit much longer before being baked or cooked without loss of leavening power. See discussion.  

Some baking powders include sodium aluminum sulfate or aluminum, but there are aluminum-free ones that work just as well, which I prefer; powders made with aluminum lend an unpleasant flavor to delicately-flavored baked goods. (No health risks have ever been directly linked to its inclusion). Look for a brand like Rumford's at natural food stores and many supermarkets, which I highly recommend.  There is also a low-sodium baking powder made by Featherweight, but it costs twice as much.

Baking Soda: fine granular powder, sold in prepackaged form Baking soda was not available until the early 1800s in the United States.
bulletUsed in making quick-breads, cakes, cookies and other related baked foods
bulletNeeds an acid to be activated
bulletUsually mixed in with the dry ingredients
bulletThe CO2 released from the baking soda merely expands the air bubbles previously formed in the batter or dough from whipping, beating or mixing, etc., making the baked good rise. 

BAKING SODA: Baking soda (bicarbonate of soda), another chemical leavener, is used when there is an acidic ingredient in the recipe, such as vinegar, lemon juice, sour milk or buttermilk. The acid might be hidden such as in honey and molasses. 

Acidic ingredients include: applesauce, buttermilk, honey, brown sugar, molasses, cream of tartar, lemon juice or vinegar, chocolate and cocoa powder (only regular cocoa, not Dutch-process).  

When baking soda comes in contact with an acidic ingredient and is moistened, the alkali/acid combination creates carbon dioxide (CO2), water and a neutral salt. It also renders a neutral, tasteless residue. 

If the level of baking soda is too high in the recipe, it creates soapy off-notes. If the level is too low, it will allow the acidic flavors to come through. Excess levels also result in over-browning. 

Air bubbles are not created by the chemical leavener; they are simply enlarged by them, formed during creaming, mixing, kneading, beating, etc. The finer the air bubbles are beaten in, the finer the resulting baked good's texture will be. But, be careful --  sometimes too much beating, as in quick-breads, causes a tough recipe.

HOW CHEMICAL LEAVENERS WORK: Baked goods, leavened with baking soda, baking powder and the like are known as chemical leaveners (as opposed to yeast, a natural leavener), purchased from the grocery store. They raise and aerate batters and doughs by expanding the air bubbles created in them through mixing, beating, whipping, stirring and kneading. These millions of bubbles are trapped in the batter by the gluten structure formed and are enlarged by the leavener, either triggered by moisture and/or heat. In most cases you want to balance the leavening system to achieve a neutral pH.  

When I created 125 recipes for my Healthy Oven Baking Book, getting the right balance of the leaveners was the hardest task. (For recipes from my book, go to to Recipes, where my healthy ones are highlighted in purple). Although there are rules for how much baking powder or soda you should add per cup of flour, these rules are really only guidelines. I would call my food scientist, Carol Lloyd, who consulted with me, and report: "I don't like the texture of my chocolate chip reduced-fat cookie or the color of the chocolate cake". She could often be heard saying: "Try adding 1/4 teaspoon baking soda" or with cookies, "Take out the baking powder, leave in the baking soda and see what happens". Creating recipes really takes a lot of trial and error, the knowledge of leaveners--and baking !! (With my White Cake Recipe, I baked it 100 times to get it right!).  

What distinguishes one from the other has to do with the speed and timing of the leavener. Baking soda begins to create carbon dioxide gas when moistened. Double-acting baking powder (which most baking powders are these days) produces an initial set of gas bubbles when mixed with wet ingredients and then a second set when heated. The first reaction forms many small gas cells in the batter; the second reaction expands the bubbles to create a light texture. In the oven, heat not only assists these reactions, but also transforms the water in the recipe into steam that also contributes lift.

Question: I know you recommend buttermilk when making (homemade) cornbread. Is it also preferable to use buttermilk when using a commercial cornbread mix?

Answer: I like to use buttermilk in recipe because it gives a nice mouthfeel, but I always balance the leaveners along with it.

It's best to use whatever the baking mix calls for. The leaveners in the recipe are formulated to activate based upon the pH of the ingredients. If the boxed mix said to add buttermilk, the batter's leaveners are formulated to counteract its acidity. The baking soda in the mix activates from the acid, provides carbon dioxide for leavening and at the same time neutralizes the flavor of the acidity in the batter giving you a nice taste and texture (too much acid in a batter would give you a craggy and uneven texture). If you added milk instead, the recipe would taste almost bitter or salty from the unneutralized baking soda in it unless it had baking powder instead.

When carbon dioxide is released by either baking soda and/or baking powder, it first dissolves in the batter's liquid. When the liquid becomes saturated, the carbon dioxide begins to evolve into the air bubbles, causing them to expand. The bubbles continue to expand as long as the batter is not fully baked. When the batter sets into a firm structure during baking, the aeration is preserved which you see as the tiny air holes throughout the recipe.

Baking soda is four times as strong as baking powder. The general rule is to use 1 to 1-1/4 teaspoons baking powder per cup of flour. On the other hand, baking soda should be added at 1/4 teaspoon per cup of flour.

Note: However, if you have a recipe that works and the above ratios are not followed, DO NOT adjust the recipe.

If you add an acidic ingredient (Chocolate, honey, molasses, citrus juice, sour cream, buttermilk and brown sugar, natural cocoa powder etc.) to a recipe, adjust the leaveners:

Adding buttermilk (an acid) instead of milk: if the recipes uses 2 teaspoons baking powder, and you add 1/2 cup buttermilk, instead use 1 teaspoon baking powder + 1/4 teaspoon baking soda or 1 teaspoon baking powder = 1/2 teaspoon baking powder + 1/8 teaspoon baking soda

Note: Many times, other ingredients have to be changed as well when substituting ingredients, such as sugar, flour, fat, etc. It is not as simple as it looks.

THE BAKING POWDER AND BAKING SODA SWITCH-A-ROO:  

QUESTION: Why do some brownie recipes with Dutch-process cocoa powder use baking soda? I thought that only baking soda is supposed to be used in the presence of an acidic ingredient, such as natural cocoa powder, buttermilk and brown sugar.

ANSWER: There is a lot of confusion about baking powder and baking soda and their use with Dutch-process or Natural Cocoa Powder and chocolate. It is a tough subject to grasp because there are so many opinions. Besides leavening, baking powder and/or baking soda contribute to texture, color and taste in a recipe.

Q: WHY IS HOT WATER USED IN SOME CHOCOLATE CAKES?
A: The use of hot water is utilized in chocolate cakes in two ways. Sometimes you will see the cocoa powder dissolved in warm water before it's added to the recipe. This helps dissolve it better for more cocoa flavor.

Then, there are recipes where the leavener is added to the hot water at the end of the recipe, ie: add the baking soda to the hot water, and add to the rest of the batter. That is done just for color. Baking soda is added not only to a recipe for leavening, but will also enhance color. When added to water, it expenses the leavener, but changes the pH of the recipe, enhancing/darkening the color of the cocoa powder in the recipe. If there is baking powder in the recipe, as well, that's what in fact, leavens the recipe, plus any left-over baking soda not expensed.

I gained a lot of experience concerning leaveners and their use with cocoa powder and chocolate when I developed chocolate recipes for my Healthy Low-fat Baking Book and 2 mixes for my 12 flavor product-line, Healthy Oven (found nationwide for 10 years in grocery stores. Healthy Oven no longer being made--hard to make a profit). Two chocolate mixes, The Chocolate Muffin Mix and Chocolate Quick-Cake Mix, both made with Dutch process cocoa powder, were the toughest to create because of the contribution that the baking powder and baking soda made to the outcome.  

Baking Soda: Using natural cocoa powder (an acid) in a recipe, calls for baking soda (an alkali).

Baking powder: Baking powder is used when there aren't any acidic ingredients in the recipe and helps to make its texture more tender. Dutch-processed cocoa, also known as alkalized cocoa (nonacidic ingredient), is treated with a mild alkali, such as baking soda, to neutralize its acidity. 

Baking powder is also found when used with chocolate, such as in the Thick Chocolate Fudge Brownie Recipe. Baking soda would give a harsh taste and would color the tops of the brownies a very dark brown, not very appealing.

Exceptions: With some recipes that have acidic ingredients, the use of baking powder is preferred instead of the customary baking soda. It is used in the recipe because it enhances flavor or retains the "tang" of an acidic ingredient, such as buttermilk.

Baking soda is used to produce the rich red color in the Red Velvet Cake that calls for Dutch-process cocoa. Vinegar and buttermilk, both acidic ingredients are added because the baking soda needs it to react. If the same recipe used baking powder, the cake would have a brown crumb color and probably taste bitter. 

High altitudes affect the amount of baking powder needed in a recipe. Atmospheric pressure affects the reaction of carbon dioxide. Air pressure is lower at higher altitudes, the carbon dioxide expands more; and thus, less baking powder is needed. If you do not cut back, the texture will be rougher.

In my Reduced-fat Chocolate Chip Cookie Recipe where it has some brown sugar, an acidic ingredient, I use baking soda for leavening. But, it also helps the cookie bake faster, become chewy and moist in the absence of fat. Because it raises the pH in the recipe, it also brown betters. 

Baking Soda and Baking Powder: Both baking soda and baking powder are used alone or in some recipes or you'll see a combination of the two, such as in Tami's Classic Chocolate Cake.  Recipes that call for both are probably using the baking soda to offset extra acidity in the batter (from ingredients like buttermilk or molasses) and to weaken the proteins in the flour. Omitting the baking soda from this recipe will alter its color or flavor and make it less tender.

CREAM OF TARTAR

EGGS

MECHANICAL: The mechanical action of the whip, tool, hand, etc. will incorporate tiny air bubbles into the recipe. These air cells will expand during the baking process from the leaveners, causing the recipe to rise. Usually a doubling of volume is desired. The proper whipping of the product and the proper incorporation of air into the batter are of utmost importance to the leavening of the final recipe.  Mechanical leavening is achieved by using different mixing techniques. Examples are:

bulletCreaming butter and sugar. 
bulletKneading, mixing, beating and stirring. 
bullet Whipping eggs, such as egg yolks and sugar or egg whites. 

SOURDOUGH & SPONGE STARTERS

STEAM: Steam leavened recipes include pate a choux and popovers. The crust traps steam inside, generated from its ingredients. It is this principle, that causes them to become inflated, hollow and stay puffy if properly baked. 

YEAST

QUESTION: While baking the other day, my husband asked me a simple, yet direct question and I had no answer. Can you help me out please? This was all over a loaf of bread, and why, if baking soda can make "stuff" rise...why use yeast? My generic, but always convenient excuse..."Because the recipe calls for one or the other!" Now, can you help me out here?

ANSWER: Yeasted breads: Natural leaveners, called sourdough or wild yeasts were in use thousands of year's ago, before chemical leaveners, such as baking powder or soda were. Bread making continued on its way through generation after generation, and because of tradition, still remains the same.

Today, we use packaged yeast and some still make a sourdough starter as the bread's leavener. But, all yeast works the same - yeast is a living organism and releases its leavening power over several hours, which is slower than chemical leaveners. This gives the bread the attributes that we all love in a homemade loaf: a yeasty smell and taste, a certain texture and crust.

Breads are usually made with a high-gluten flour, usually bread flour or all-purpose that is kneaded and a strong structure is formed; a high gluten flour, when mixed with water or moisture and stirred forms an inner network, like a net, called gluten strands, that trap air bubbles. They later expand from the heat and gasses released from the leaveners.  

If baking soda or powder were used in bread recipes, it wouldn't rise at all; baking soda or powder are not strong enough to push the bread's structure to new heights, called rising. 

Chemical leaveners came about later and recipes were developed to use them, such as for quick-breads, pancakes, cookies, cakes, etc. They can be mixed more quickly and then baked immediately, unlike yeasted breads which require several hours to make. Their texture derives from the leavening and mixing techniques used, and the taste from added flavorings and ingredients. 

If you used yeast in cake, etc recipes, the batter would bubble and drip all over your oven. The flour used, usually cake or all-purpose, is lower in gluten than bread flour. The resulting gluten strands formed during mixing, beating, stirring, etc. with water or moisture, couldn't trap the air bubbles formed from yeast's strong leavening powers. But, it can in a recipe leavened with baking powder and soda.

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