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Chocolate 

Introduction: Melting & Tempering

                       

Problems

         

Introduction: Important rules to follow when melting or tempering chocolate: 

Chocolate comes in the form of a large, hard bar, one ounce squares or chocolate wafers, either as dark, white or milk chocolate. When making chocolate confections and desserts, it is necessary to either melt or temper it in a certain way depending upon the type and recipe, which I show you how. When I discuss large amounts of chocolate, I mean: about 1/3 pound and more or 5 or 6 chocolate squares. Happy Baking, Sarah

MELTING is defined as using indirect heat to convert chocolate from a solid to a liquid, such as done when melting butter. It is done when making recipes with a couple of ounces of chocolate squares or when working with a 1 pound or so for tempering. If used in baking recipes, it then cooled to tepid and blended in with the rest of the ingredients or cooled slightly to used in a variety of simple chocolate decorations

Keep melted confections at room temperature. If the storage area is warm, the freezer is a better place to store them than the refrigerator.

TEMPERING is a technique by which pure chocolate is stabilized through a carefully controlled melting-and-cooling process, allowing the cocoa butter molecules to solidify in an orderly fashion and for the chocolate to harden properly. Commercially available chocolate that you buy is already tempered, but this condition changes the minute you melt it for your own use; the molecules of fat separate (as cream separates from milk). In order to put them back together, you must temper it.

QUESTION: If white chocolate doesn't contain cocoa solids, and is technically not considered to be chocolate, why does it need to be tempered? ANSWER: White chocolate does contain cocoa butter, and tempering has to do with cocoa butter crystals.

Tempering is important because it determines the final gloss, hardness and contraction of chocolate. At each step of the tempering process the temperature of the chocolate must be precise and uniform: even tiny variations can ruin the result. 

Tempering isn't necessary for all recipes, but is done when the chocolate will be used for candymaking, such as molded chocolates or dipped centers, as well as for more extensive decorations, such as sculpted ones or ribbons. Without tempering, the chocolate does not harden properly as the cocoa butter separates out. If you do, the chocolate is more malleable and glossy when it sets. 

To store tempered chocolate confections, keep them at room temperature. If they're tempered properly, they should be fine. Don't put them in the fridge because they will "bloom"-- that's the cocoa butter starting to separate out from the chocolate, and it forms a thin layer of cocoa butter on the surface. They're totally fine to eat if they bloom, they just don't look gorgeous. Fat absorbs heat at a different rate than the other ingredients in chocolate, so it's unstable and floats to the surface, like cream floats to the surface of milk.

TYPES OF CHOCOLATE USED FOR MELTING OR TEMPERING: 

Type No Tempering Required Must Be Tempered 
Chocolate with No Added Ingredients Also referred to as pure chocolate, it contains cocoa butter in its pure state, so must be tempered before using. When it is used as part of a baking or candy recipe where other ingredients are added, it need not be tempered. Examples are the Chocolate Cake Recipe or the Chocolate Ganache Recipe. Another example is when making candy such as clusters or bark, where nuts and/or chopped candy are included. Small designs do not require tempering, unless you want a smooth gloss. The Peanut Butter Chocolate Truffle Recipe doesn't either, however some you'll often see tempering the chocolate coating as part of a truffle-making step. It is recommended when making large chocolate decorations or molded chocolates.  Recipes such as the Chocolate Truffle and the Classic Chocolate Dipped Strawberry Recipes use it. 
Couverture For dipping, a good quality chocolate such as couverture (or "covering") chocolate which contains at least 32% cocoa butter, will give you the best smooth and glossy coating. It may be difficult for some to work with.

Couverture has a high proportion of cocoa butter and other fats, tempering is necessary to give the finished chocolates a crisp and glossy finish. 

Pure with Added Ingredients Tempered chocolate cannot be used for retempering if ingredients have been added to it, such as oil or cream or has been used to dip fruits in, such as strawberries; but it can be used for making ganache or in baking recipes. --
Chocolate Chips  When you buy the chips, they have already been mixed with other ingredients, and are not pure. They can be simply melted. The Chocolate Covered Pretzel Recipe is an easy way to coat pretzels with chocolate.  --
Compound or Summer Coating  Does not contain cocoa butter, so does not need tempering --
Candy Melts To melt Candy Melts‘, use a squeeze bottles or disposable decorating bags. Melt candy melts in microwave on half power or defrost setting for one minute. Squeeze bag or bottle to blend. Continue to heat at 20-second intervals on half or defrost power until candy melts are completely melted. If using the decorating bag, be sure to cut the tip prior to filling candy molds. --
Chocolate and Paraffin (Parawax or Cooking Wax) - Parawax is the same thing as paraffin and can be found in the grocery store, usually in the preserves section or the cake section. It is inexpensive. Some older recipes for dipped candy call for melting paraffin with chocolate to make it firmer and give it a nice sheen upon cooling. The label on most paraffin boxes state it is not for human consumption, but it is still used. --

BEFORE YOU START MELTING OR TEMPERING CHOCOLATE:

GENERAL TEMPERATURE GUIDELINES WHEN WORKING WITH CHOCOLATE:

Melting and tempering is done at certain temperatures, as measured with a Chocolate Thermometer. The lighter in color the chocolate, the more easily it burns.

Chocolate melts best at temperatures between 104 and 113 degrees F (40 and 45 degrees C). The process starts around the low 90s degrees F when the cocoa butter in it starts to heat. Melting temperatures must never exceed 115 degrees F (milk and white) and 120 degrees F for dark, otherwise it will burn.

Sometimes the best temperature is printed on the chocolate's label. But, for home baking, most recipes have you heat it until "it melts".  I find that it's best to melt chocolate until it almost melts, then remove from the heat source and stir until all of it is melted. This prevents the chocolate from burning.

If you can master the art of chocolate making, you can create some breathtaking desserts and I will show you how. Before starting, make sure you have the time to pay undivided attention during the whole process of melting or tempering.

The key to successfully melting or tempering chocolate is to do it gradually with indirect, very low heat, while gently stirring until the chocolate is almost melted. Remove from the heat source and stir until it melts completely. It may take awhile, but do not put it back on the heat source.

Make sure no beads of moisture are allowed to mingle with the chocolate while melting or it will become a grainy, lumpy mess called seizing. If this happens, you can try adding a little vegetable oil and heating the two together for use in a recipe, but it doesn't always work. Once vegetable oil is added it can no longer be tempered.

Milk and white chocolate are especially sensitive to heat, more than dark. White chocolate is the most delicate to work with because it contains milk solids. The chocolate can easily lump up if exposed to too much heat. They are really unmelted chocolate. Most turn up the heat, which causes further problems.

Q: How much should the melted chocolate cool before I fold in the beaten eggs?
A: Ideally, the chocolate should be tepid. If the chocolate is too hot, the eggs curdle!

What if your recipe calls for melting chocolate along with water or some other type of liquid? If fat, such as oil, clarified butter or vegetable shortening, or a liquid is to be added to melted chocolate, it's best to add it with the chocolate before heating, otherwise the chocolate will seize. This is can be done to make the chocolate thinner, as in the Chocolate Dipped Strawberry Recipe. 

If using melted chocolate in a recipe, cool it first until tepid or 100 to 105 degrees F (slightly warmer than body temperature, which is 98.6 degrees F). Also, make sure any ingredients are at room temperature before adding it to the chocolate or the chocolate to it. The chocolate may seize if shocked by cold ingredients.

Per capita, Americans eat an average of 26.2 pounds of candy each year, split almost equally between candy and chocolate. Chocolate is America's favorite flavor. 

If using melted chocolate for molding or tempered chocolates, work quickly to use it. Properly tempered chocolate will start to set up in 5 minutes, and if placed in the fridge will turn hard in about 5 - 6 minutes if small. 

Chocolate must be properly stored because it is sensitive to temperature changes. Always wrap chocolate well and store in a cool, dark place away from odors. For more, go to Chocolate Basics. Never refrigerate it, unless it is hot and humid. If not properly stored causing the chocolate to melt and resolidify during storage, you see a milky "bloom" on the outside. If it does however, you can still use it in baking recipes.

MELTING OR TEMPERING CHOCOLATE:

Chocolate is as temperamental as it is wonderful. The two most common problems of working with chocolate are separating and seizing. There are steps to follow which ensure that neither separation nor seizing occur: 

Separation happens when the cocoa butter separates from the solids because it is heated too hot. An indication is a gray film, called bloom, that you will see on the outside of the hardened chocolate, when cooled and there is no way to salvage it. Instead, use gentle heat and don't forget to stir. 

Seizing is what happens when chocolate clumps and becomes stiff and grainy from moisture being introduced or the chocolate burns. You can fix it sometimes, but then it becomes unusable for anything except baking recipes. 

Steps to Ensure Successful Chocolate Melting or Tempering:

1. The work area should be about 68 degrees F maximum. That's so the chocolate will set up properly; if too warm, it won't. Also, work surfaces and equipment should be clean and dry.  Also, equipment used must be of the room temperature. For more, go to Chocolate Basics.  

2. Use top-quality chocolate. It will really make a difference in your recipes. I like to use dark bittersweet for both Valrhona for tempering and enrobing and Callebaut for ganache. (Callebaut is a bit thicker than Valrhona). For baking recipes, I like bittersweet Baker's or Hershey's chocolate squares, available from the grocery store. But, find a chocolate you like and stick with it. 

3. Any type of chocolate is measured by weighing. For accurate measuring, weigh chocolate before and after chopping. If using 1-ounce baking chocolate squares, no need to weigh. 

First weigh the container the ingredients will go into. Set the "zero" indicator where the bowl's final weight is. Then, add the ingredients to the bowl, and weigh again to get the chocolate's weight. In effect, you have ignored the weight of the bowl and included the weight of the chocolate, which is the proper way to do it. Weigh the amount you will need. Chop the chocolate, and weigh before using to make sure you have enough.

Stirring chocolate is very important. The chocolate should slowly begin to melt. Try not to disturb the chocolate during this process. A few stirs with a heat proof rubber spatula (not a wooden spoon) near the end of the process should help mix the melted chocolate. Then proceed with more vigorous stirring. 

Reasons for stirring: 

bulletOne of the major causes of the chocolate separating is inadequate stirring, which allows the fats and solids to break apart. Proper stirring keeps and even temperature throughout and encourages gloss and hardness when it sets after tempering.  
bulletWhen removed from the heat, the stirring action causes the chocolate to cool faster.
bulletStirring evenly distributes the melted chocolate in the bowl. Always stir vigorously for 1 minute before measuring with a Chocolate Thermometer; it gives a more accurate temperature reading. 

If tempering chocolate, at a minimum use least 1 to 1-1/2 pounds of chocolate; any less will be apt to burn. 

4.  Optionally, chop chocolate before melting. No need to chop a few 1-ounce squares used for baking recipes, unless the recipe states.  

Always make sure all dipping and stirring implements are moisture free as any moisture and can cause the chocolate to seize. Use a dry, heat-proof rubber spatula -- it is preferred for stirring chocolate as opposed to a wooden spoon, which usually contains moisture. 

However, when melting pieces cut from a large bar, cut off a section and coarsely chop with a sharp, serrated knife into EVENLY sized 1/4-inch pieces. This is so the chocolate will melt pretty much at the same time; you don't want some of the chocolate to burn while the other pieces are still not melted. To learn about how to chop chocolate, click here.

I do not recommend using a food processor for chopping chocolate because during the process it can melt easily and make a big mess -- which I know from personal experience! Chocolate can be grated and does so more easily if frozen first (not refrigerated), but it also makes a huge mess. I like to use microplane for grating chocolate, as it works better. 

Chocolate's temperature when tempering must be accurately measured, so a Mercury-Gauge Chocolate Thermometer is a must ! (Other recipes sometimes call for it, as well). Because chocolate must be measured in 1-degree increments, this type thermometer is important.

A chocolate thermometer is best used when measuring large amounts of chocolate (about 1/3 pound and more or 5 or 6 chocolate squares).

For small amounts of chocolate used in baking recipes, there's no need to measure with a Chocolate Thermometer; just watch carefully and remove from heat when just melted. Keep stirring until fully melted.

A chocolate thermometer is available from cookware stores. Only use a digital pocket thermometer or an instant read dial thermometer if it comes with l-degree increments. Do not use a candy (deep fat frying) thermometer because the temperature gauge does not register finely and/or low enough.

To use a chocolate thermometer: Always stir the chocolate vigorously for at least 1 minute before inserting the thermometer and continue to stir towards the thermometer during the reading. 

When using, do not let the tip of the thermometer touch the bottom or sides of the bowl because this can give a false reading.  

TO FIX SEIZED CHOCOLATE: If chocolate "seizes", immediately whisk in a little VEGETABLE OIL until it becomes smooth again. (It sometimes works!) Once seized, the chocolate can no longer be used for tempering because it is no longer considered to be pure.  It can be used in a recipe if it isn't burned.

When melting chocolate for a recipe, the easiest way to avoid seizing is to melt 1 tablespoon of liquid from the recipe with every two ounces of chocolate.  

Sometimes chopped chocolate is melted by pouring hot liquids over it, such as heavy cream. This is done when making Chocolate Ganache.

5. Use a Chocolate Thermometer to help you keep track of its temperature right after melting and during the chocolate's use.  

Chocolate burns easily and must be watched carefully and stirred while melting, tempering or reheating. Burned or overheated chocolate is grainy and has a burned after taste. You can even see and smell it. If chocolate burns, you have to discard it as it can no longer be used. 

THERE ARE DIFFERENT WAYS TO MELT CHOCOLATE: Never place chocolate directly in a pan over heat. Because of the sensitivity of milk solids to heat, chocolate is best melted in a double boiler, in the oven or if you have small amounts, in the microwave. White chocolate will burn more easily than bittersweet or dark chocolate.sauce pan and bowl

1. Melt chocolate is in a double boiler, or one you fashion yourself.  

Melting chocolate in a double boiler applies to all chocolate in both small and large amounts. It is a two part pan, with one stacked on the other. You can also make your own.

Fill the saucepan on the bottom with an inch or two of water and let it boil. Turn off the heat and remove. Wipe off the top if the pot. Because chocolate is moisture adverse, you want condensation, stem and splashes to be minimized to prevent it from seizing. Water will separate the chocolate and can ruin the batch.

MELTING MILK AND DARK CHOCOLATE WITH OTHER INGREDIENTS: You can melt chocolate and other liquids together, such as water, but there are some rules. You can't melt a large amount of chocolate with a small amount of butter or cream - you need to have the right proportions to prevent the chocolate from seizing. The rule of thumb is, the minimum is: 1 tablespoon water-type liquid for every 2 ounces of chocolate.

4 tablespoons of butter = 1 tablespoon of water (butter is about 18% water)

4 tablespoons liqueur = 1 tablespoon water

5 large egg yolks = 3 tablespoons water

4 tablespoons cream = 3 tablespoons water

Shortening is 100% fat and does not contain water, so you don't need to be concerned about the chocolate to water ratio when you use shortening!

(So, you can melt chocolate and water together, if you keep the above ratio!)

Chopped chocolate is placed in the top portion, placed over the bottom part and stirred constantly. The chocolate melts from the indirect heat coming from the steam below. Make sure the water below doesn't not touch the bottom of the top pan because its considered direct heat if you do. Melt chocolate uncovered as moisture can condense on the lid, fall back into the chocolate causing it to seize

Some bakers place the chocolate over barely simmering water, which I recommend if you are experienced. It is done by heating the water almost to boiling and then lowering the heat so it simmers. The bottom portion's rim is wiped off. The top portion with the chocolate is placed on top. Others turn off the simmering water half-way through melting, and continue to stir until melted. But, I prefer to heat the water in advance so you don't run the risk of scorching the chocolate or have it seize

If you don't have a double boiler, you can fashion one yourself. Take a heat-proof glass or an aluminum mixing bowl. This becomes the top part of a double-boiler, that is set over a short, straight-sided, wide saucepan, which is the bottom part.

For the top part of the double boiler, use a fairly big wide bowl, not a small deep one -- you want as much of the surface of the chopped chocolate to be exposed to the steam from the hot water below and melt at the same time. You can also stir it more easily and vigorously that way. 

TO MELT CHOCOLATE WITH PARAFFIN: Some recipes call for adding paraffin wax so the chocolate hardens with a sheen. It is perfect when working with small amounts of chocolate, such as dipping cookies or fruit. However, paraffin is not necessary for successful dipping and you may not like its flavor. If you are using top-quality chocolate, it already has everything in it that you need. Paraffin is found in the grocery store.  

NOTE - Do not leave the melting wax unattended or use high heat when melting because it is highly flammable. 

WARNING: Melt the chocolate and the wax, but do NOT try to melt the chocolate and wax together (unless using chocolate chips), as it will not work.   

1. Melt the chocolate. Remove from heat. 

2. Melt the wax in an uncovered pot over very low heat. It doesn't take that long, so watch carefully. Remove from heat. 

3. When both the chocolate and the wax are still molten, but cooled slightly, pour the wax into the chocolate slowly, stirring constantly. Stand back while doing so or don't look into the pot directly; you don't want either to splash and hit you -- both are VERY HOT. 

TO MELT CHOCOLATE CHIPS WITH PARAFFIN - can melt together: I use 1/4 bar (1-ounce) paraffin wax per 1 (12-ounce) package of semisweet chocolate chips. I use this also when making Christmas candies.  Just melt it with the chocolate in the top of a double boiler over hot water.

A cookie dipping example: To dip Spritz cookies, hold a cooled cookie at an angle - from corner to opposite corner - and dip into the melted chocolate/wax mixture. Set aside on a wax paper covered cookie sheet. When all dipping is completed put the dipped cookies in the refrigerator for about 30 minutes to quickly harden the chocolate.  

Be certain that about half of the bowl can be inserted into the saucepan. You want it to cover the entire top of the pan so moisture can't get out from condensation from the water below and cause seizing

When the chocolate is almost melted, immediately remove the top portion, dry off the bottom and sides and set aside.  Don't pour out the hot water just yet. Stir the chocolate vigorously with a heat-proof spatula so all the chocolate melts; it may take a bit but all of it will eventually melt. If it isn't working, set the chocolate over the hot water again and let more melt. 

If you want melted chocolate to pour over something cold, like ice cream, do the following: after melting and while still warm, add 1 tablespoon vegetable oil, like canola oil. Stir vigorously until combined. The chocolate won't turn hard right away when it hits the cold.

2. The no water technique -- melting chocolate in an oven as inspired by my mom. Place chopped chocolate in a heat-proof  bowl and place it in an oven set at 110 degrees F (if your oven doesn't go that low, use the lowest temperature and keep the door ajar). Your chocolate will melt in about an hour. 

Another way is to melt a few chocolate squares while your oven preheats, but watch it very carefully. Place in a heat-proof bowl or in a piece of aluminum foil with formed raised sides (so the chocolate won’t run off the foil) on the middle shelf. It will take 5 to 10 minutes for them to melt. Remove when almost melted (it will still retain its shape and look shiny) and stir until all of it is. 

3. Chocolate can be melted in a microwave oven which is best for small amounts, only. Because milk and white chocolate contain milk proteins, they can overheat quickly and become grainy. They need to be removed from the microwave and stirred sooner than dark chocolate.

Place one ounce of more of finely chopped chocolate or chocolate chips in a microwave-safe bowl. When it is about 85 % done, take it out and stir and the rest of the chocolate will melt. 

To do: Microwave on medium (50 percent) checking every 10 - 15 seconds. Chocolate holds its form and looks shiny (it won't look melted), so stir several times to check. Let it stand for thirty seconds with the microwave turned off. Remove the container and stir the chocolate until completely melted.

From Hershey's Chocolate:

Product Amount
Temp
Time
Procedure Additional Time
HERSHEY'S Unsweetened or Semi-Sweet Baking Chocolate (4 oz.) 4 bars
High
1 Min. Stir until melted Check at 30 second intervals as needed
HERSHEY'S Butterscotch Chips, Cinnamon Chips, Premier White Chips, Raspberry Chips, MINI KISSES Semi-Sweet or Milk Chocolate Baking Pieces 1-2/3 cups (10-oz. Pkg.)
High
1 Min. Stir until melted Check at 15 second intervals as needed
REESE'S Peanut Butter Chips HERSHEY'S Milk Chocolate Chips 2 cups (11.5-oz. Pkg.)
High
1 Min. Stir until melted Check at 15 second intervals as needed
HERSHEY'S Semi-Sweet Chocolate Chips, OR MINI CHIPS Semi-Sweet Chocolate 2 cups (12-oz. Pkg.)
High
1-1/2 Min.
Stir until melted Check at 15 second intervals as needed
HERSHEY'S Classic Caramels 60 pieces
High
1 Min.
Stir until melted Check at 30 second intervals as needed

6. You're now ready to use the melted chocolate to create confections or decorations. Check the temperature one more time and remember to stir before doing so! If you used dark chocolate, the temperature should be between 85 and 90 degrees. If you used white or milk chocolate it should be around 85 or 86 degrees.

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