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Enrobing is taking tempered chocolate and coating a candy, dried and fresh fruit, a nut or even a cake slice. The result is a center or cake piece that is covered in chocolate to be eaten as a confection.

HOW TO ENROBE:

bulletNuts 
bullet Truffles
bulletFondant Centers
bulletNuts
Dipping or coating is another form of covering with melted or tempered chocolate. Strawberries, pretzels, cookies and other confection's are dipped in molten chocolate, immediately removed and then cooled.

HOW TO DIP:

bulletFresh Fruit
bulletCookies
Using a Mold is a way of taking melted or tempered chocolate, pouring it into a form, optionally filling it, and removing when set and cooled. Here, the hardened chocolate's shape conforms to the mold. 
HOW TO USE A MOLD:
Classic Molds:
bullet Solid
bullet Filled
bullet Hollow
Creative Molds:
bullet Cookie cutters, etc.
bullet Chocolate bowls
bullet Chocolate leaves
bullet Marbleizing
bullet Painting

Problems with Solution

GENERAL TIPS WHEN ENROBING, DIPPING, COATING & MOLDING: For best results, the chocolate used should be tempered. But, depending upon what you are making, sometimes melting is all that's necessary. It's best to at least temper 1 pound to a 1-1/2 pounds. Remember you can "reuse" chocolate over again! Store in a cool dry place, NOT in the refrigerator. 

bullet Tempering chocolate is a three-step process of melting, cooling and rewarming at precise temperatures, which stabilizes the chocolate, so it hardens properly. Its best used when making molded chocolate pieces, enrobed candy or free form designs. Tempering makes it harden better, with a smooth and shiny gloss. The chocolate will also break with a snap. The Chocolate Dipped Strawberry Recipe is an example of using tempered chocolate.
bulletIf you wish to avoid tempering when dipping chocolates, there are other ways to do it. But, it isn't a guarantee that it will harden with the same good qualities that tempered chocolate does. Chocolate chips are often used in some recipes, and melted  with added cream as in the Chocolate Covered Pretzel RecipeCoating chocolate, a much used chocolate-flavored product, does not need to be tempered and will fully harden. It is easier to work with, but falls short of genuine chocolate in terms of taste and texture. 

If the chocolate is too hot or too cold and thick, it wouldn't work well while enrobing, dipping and molding:

bulletWhile using tempered chocolate, for best results it should remain in the temperate zone of 84 to 91 degrees F (dark) and 86 to 87 degrees F (white), as measured with your Chocolate Thermometer; the best dipping temperature for dark is around 88 degrees F and 86 degrees F for milk and white chocolate, however every recipe varies and you'll have to do a test. It must be stirred every few minutes and have it's temperature checked often. If the chocolate is too hot or too cool or thick, it wouldn't work well. 
bulletIf chocolate cools to or lower than 84 to 85 degrees F and is still melted, you can reheat it multiple times back to "temperate zone" of 88 to 91 degrees F (dark) or 86 to 87 degrees F (milk and white). Reheating happens quickly, so watch the chocolate carefully. If it is accidentally heated above the temperate zone or below, the tempering process must start again. 

Cooling Enrobed, Dipped & Molded Chocolate:

For most chocolates, the best temperature to cool chocolate to is 59 to 64 degrees F (15 to 18 C). The freezer (5 - 10 minutes maximum) is better than the refrigerator (15 - 30 minutes maximum). There are several ways to cool chocolate:

bulletA freezer, the best option to use when cooling chocolate pieces. It "quick cools" the chocolate and making it easier to remove it from the mold, giving a better, shiny surface finish. Do not wrap when  cooling; only when storing long-term. Filled molds can also be put into the freezer (on a flat surface). Small candies or bite size items will be ready to remove in about 5 minutes; standard larger pieces in about 10. Leaving it in the freezer longer than necessary is no problem at all, but if you do, after the chocolate has set, wrap it in saran wrap and then in an airtight container.
bulletYou can also place the unwrapped chocolate in an area which is cooler than the kitchen. This will give the first hardening to the chocolate, but the freezer is really better. 
bulletIf you must, you can use the refrigerator instead of the freezer, but it will take about 3 times longer to cool the chocolate sufficiently. A refrigerator has more moist environment than a freezer, not a good place for chocolate. 
When the chocolate sets: As the coated centers cool, they should become shiny if you did everything correctly. It they don’t get shiny, don’t worry too much about it, just take your time tempering on the next batch. The flavor will be the same even if you did not get the temper right and you will soon get the “feel” of the chocolate as you continue dipping.

Chocolate keeps best at a temperature of 54 to 68 degrees F or in the freezer for longer storage or if it is warm. A dry, odorless cellar or unheated room is the ideal place. If possible, keep the chocolates in an airtight container. And avoid storing them next to food with strong odors. DO NOT REFRIGERATE unless absolutely necessary. The freezer is a better place than the refrigerator because it is not a moist environment, best for storing chocolate or chocolates in. To freeze already set chocolate, place in an airtight container and freeze. (Don't forget; chocolate will easily take on other odors in the freezer, so I also place my container in an airtight bag). Before serving, remove container and let the chocolates warm to room temperature in it; that way the condensation that forms stays in the container, not on the chocolates.

For enrobing, dipping and molding, you need the following: 

bulletMolds: I like to use the hard plastic molds. They should be clean AND dry before using. They are NOT dishwasher safe!  Buff with a lint-free soft cloth before filling with tempered chocolate; it gives the chocolate a nice shine. Either spoon it into the mold cavities, or gently squeeze the chocolate out using a heat-proof squeeze bottle.
bullet Temper: about a pound to a pound and a half of chocolate. This will ensure that you have enough and so it won't burn during the tempering process. You can reuse hardened, previously tempered chocolate with new pure chocolate, but it must be tempered again.
bullet Double Boiler: Chocolate should never be melted over direct heat because it burns easily. A double-boiler places the chocolate over a lower source of heat, such as hot water to melt, instead.
bullet Chocolate Thermometer: Using a chocolate thermometer is a must. Chocolate is temperamental and even one degree F can make a difference between success and failure. I prefer to use a Chocolate Gauge Mercury Thermometer. Handle it carefully. Test it for accuracy EVERYTIME you use it for a new project. Boil water and remove from heat. Dip the thermometer in, making sure the bulb is immersed, while counting to 5 seconds and then take it out. Do not touch the tip of the thermometer to the bottom or sides of the pot while doing so. Without drying it off, make sure the thermometer reads 212 degrees F, the boiling point of water (at sea level). If it doesn't, compensate as necessary.
bullet Offset Spatula: It makes the job easier when making chocolate confections. The blade is set about an inch lower than the handle.
bullet Dipping Forks (optional): Used for dipping centers with, they have thin and small tines. They are very handy and can be purchased from a cake decorating store. If you don't have any, I have successfully used eating forks, instead.
bulletSqueeze Bottle (heat-proof): (Difficult to use when using tempered chocolate and trying to keep it in temper). Makes pouring chocolate into the molds neater and faster. Melt chocolate first. Let it cool slightly and pour melted chocolate into squeeze bottle. Cut off tip of squeeze bottle for easier pouring. If there is still melted chocolate in bottle that starts to harden, place bottle into a pan of hot tap water. This will keep chocolate melted until you are ready to pour again. Dry the bottle thoroughly before using or adding in more chocolate. To clean, empty remainder of chocolate in a bowl and put squeeze bottle in freezer. Take it out and squeeze the bottle, which will crack the chocolate and remove it from its sides. Empty pieces in a clean, dry bowl bowl or plastic bag.
Problems and Solutions with Enrobing, Dipping & Molding:
The Problem Origin Remedy
Difficulty unmolding
bulletThe coating was incorrectly tempered
bulletThe coating was too thin
bulletThe cooling temperature was too high
bulletExcess dried chocolate on outside of mold blocking unmolding
bulletIf the molded chocolate sticks to the mold when unmolding, it is probably too warm tempered properly. 
bulletAlways swipe the opening of the mold with the edge of an offset spatula or bench scraper to clean. Do this right after pouring the chocolate while it is still warm and fluid.
bulletIf necessary, carefully scrape excess from the mold with the edge of a small, sharp knife. (You can always smooth knife dings with a warmed offset spatula. Lightly pass over ding.
Whitening or graying of chocolate
bulletThe coating was incorrectly tempered
bulletThe coating solidifies too slowly
bulletOvercrystallized chocolate
bulletSee tempering
bulletSee cooling
Cracking when molding
bulletThe refrigerator was too cold
bulletThe coating was too thin and cooled too quickly
bulletSee cooling
Dull stains on molded candies  The molds were too cold
bulletHave molds at room temperature  
Thickening of coating while working Excessive crystallization in the chocolate
bullet Increase the temperature slightly
bulletAdd a small quantity of warmer chocolate
bulletDO NOT ADD EXTRA COCOA BUTTER
No gloss following enrobing
bulletThe filling was too cold
bulletThe workshop was too cold
bulletThe coating was not tempered properly
bulletTemperature of the fillings should be at room temperature
bulletSee temperature of workshop
bulletSee tempering
Fingerprints on finished products The chocolate has been touched with warm or moist fingers
bulletMake sure hands are dry
bulletUse thin, cotton gloves when necessary
Other Read article about chocolate problems and solutions  

chart adapted from http://www.jacquestorres.com

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