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The Basics Of Chocolate

Chocolate is versatile: it can be molded, sculpted, melted, spread, piped and chilled, to name a few. If your first dipped chocolates do not look as nice as the ones from the candy store, eat them anyway and do another batch. It takes some practice to master the tempering and dipping skills, but the more you do, the better you will get. There are basic rules to follow when working with chocolate to guarantee success, described below. Happy Baking, Sarah

Choose the right chocolate for your recipe:

bulletPick the best quality chocolate that you can afford. For more, click here.
bulletPure chocolate usually comes in blocks from a cake decorating store with smaller quantities in 1-ounce wrapped squares from the grocery store. But, you can also purchase pure chocolate wafers -- they look like large chocolate chips and you don't have to chop them. Don't confuse them with courverture or compound chocolate.
bulletBe careful when substituting one chocolate for another because they all have different cocoa butter (fat) and sugar amounts. Go to substitutions for more information.
bulletBe sure to choose chocolate that has a glossy, unblemished surface. A white dusty film on the outside called bloom, is an indication that the chocolate has been stored improperly. However, the presence of bloom does not affect its taste, but it doesn't look good. For more, click here.
I like to use dark bittersweet for both Valrhona for tempering and enrobing and Callebaut for ganache, both available at cookware or cake decorating stores. (Callebaut is a bit thicker than Valrhona). 

For baking recipes, I like bittersweet Baker's or Hershey's chocolate squares, available from the grocery store. Sometimes I buy Callebaut Bittersweet and it is excellent. For semisweet, I use are Guittard, Ghiradelli and Lindt. Ghiradelli can be bought in bars at your grocery store in the baking section. 

More about chocolate types.

Useful information & tools:

bulletA Chocolate Thermometer is essential when doing chocolate work. It measures the molten chocolate's temperature in 1-degree increments unlike a candy thermometer.
bulletA wooden handled spatula with a heat-proof plastic blade. Also, a wire whisk is good to have. Do not use wooden utensils, as they may contain water, causing the chocolate to seize.
bulletHeavy bottomed metal sauce pan fitted with a heat-proof glass bowl or a double boiler. Or, unlined copper, which is the traditional container to melt the chocolate in because it conducts the heat quickly and evenly.
bulletA large and sharp serrated knife and cutting board.

Temperature of the kitchen or work area, fillings, etc.:

bulletThe ideal temperature of the kitchen or work area should be approximately 65 - 68 degrees F and no warmer otherwise the chocolate won't set properly or will melt.
bulletThe temperature of the candies and fillings to be coated should be as close as possible to 70 to 75 degrees F if combining with other ingredients. If temperatures vary between the two, the chocolate will, when hardened, end up with a dull surface or may seize.
bulletWhen molding, have the temperatures of the molds as close as possible to that of the kitchen about 68 degrees F so you will get the best possible gloss for the hardened chocolate. If necessary, the molds can be warmed slightly in warm water; make sure you thoroughly dry them before use. 
bulletThe temperature of the cooling and storing areas should be around 65 - 68 degrees F so the chocolate will harden properly.

How to weigh and chop chocolate:

Instead of chopping the chocolate yourself, you can also purchase pure chocolate wafers, weigh and use as is -- they look like large chocolate chips -- and you don't have to chop them. They are available at any outlet that sells good, pure  chocolate. For tempering, don't confuse them with courverture or compound chocolate, which are not pure.
If using premeasured baking chocolate squares, there's no need to weigh them. Each squares weighs 1-ounce. Chop only if melting large quantities such as  6 to 8 or more.  

Large amounts of chocolate, whether from blocks or a multitude of 1-ounce squares, need to be chopped into roughly 1/4-inch pieces before melting. This way it will melt evenly and quickly, and the chocolate won't burn. It can also be grated, but I like this chopping method the best; the chocolate melts as you hold it to grate.

To weigh chocolate on a scale: First weigh the container the ingredients will go in. Set the "zero" indicator where the bowl's final weight is. Then, add the ingredients. In effect, you have ignored the weight of the bowl and included the weight of the chocolate, which is the proper way to measure.
When chopping chocolate, make sure its at room temperature; cold chocolate is too hard to cut and you could hurt yourself with the knife.

TO CHOP: If you have a large block of chocolate, it's best to cut off a portion of it to avoid cutting your hand, overhandling and melting it.

1. First remove a large piece of chocolate from the main bar:  

  1. Score it first with a sharp, serrated knife, where you want to break it; run the knife blade, in a sawing motion on top of the block where you want to cut it, to make a small trough. Sometimes it is easier to cut across a corner.
  2. Then, push knife, with the help of your left hand on the top of the blade, into the score and the chocolate will break off in a chunk. If it doesn't, the chunk may be too big. Try to cut a smaller one to start.
  3. Weigh to make sure it is the proper amount; you can place it directly on the scale. You will weigh again after chopping. Return the large block of chocolate, well-wrapped, to its proper storage area.

2. The next step is to chop the chocolate from the chunk, without overhandling it because chocolate melts easily. This is done by shaving off thin pieces from it before chopping. 

  1. Place the chocolate chunk you just cut on a dry, plastic cutting board. I don't like to use a wooden board because it may contain moisture (when working with chocolate, be moisture adverse). If you holds two equally-sized knifes together, about an inch to 1/2-inch apart, the chocolate pieces won't fly around, but they usually splinter from the main chunk any way. 
  2. Using a large serrated knife, place the handle in your right (left) hand and apply pressure with your left (right) palm on top of the blade, and push downwards along the edge of the block to shave off pieces of chocolate. It comes off more easily if you cut across a corner. Then turn the block of chocolate to the next available corner and cut again. 

3. Then, chop chocolate into approximately 1/4-inch pieces, as much of the same size as possible. Gather the chocolate pieces by scraping them with the side of the knife's blade, in a circle with the diameter almost as wide as the blade. Holding the top of the knife at the point, rock the blade briskly from point to hilt, gradually turning the knife towards you in a semicircle. Gather the pieces together with the side of the knife and repeat the process until the proper size is obtained. Do not chop into a fine texture; you have gone too far. Do not pick up the pieces with your hands, otherwise you'll soften or melt the chocolate.

4. Weigh chocolate again after chopping. Scrape the chopped chocolate into a mixing bowl and weigh. (Make sure you subtract the weight of the bowl from the total).  

Storage of chocolate & finished products:

Ideally, block chocolate should be wrapped properly and stored at a constant temperature of 55 to 60 degrees F with a relative humidity of about the same or 55 to 65% -- with neither temperature and humidity varying much. A wine cellar is a perfect place to store chocolate in as it is temperature and humidity controlled, or in a cool, dark place. The refrigerator is not recommended because it is a moist environment. However, if your kitchen is particularly hot and humid, and you can't find a cool, dark place to store you chocolate, placing chocolate in the freezer is still a better choice than refrigerating it. If refrigerated, there's a good chance the chocolate will "bloom"-- that's the cocoa butter starting to separate out from the chocolate, and it forms a thin layer of cocoa butter on the surface. They're totally fine to eat if they bloom, they just don't look gorgeous. Stored under perfect conditions, unsweetened and dark chocolate will last for up to 18 months in good home kitchen conditions; milk and white chocolate for 6 to 12 months.  
If you buy a large block of chocolate, for long-term storage in the freezer, break it up into 1 pound chunks and store separately.

Before storing, chocolate should be wrapped properly, too, so it does not come into contact with moisture. It's also important that the cocoa butter in it does not pick up any odors or dry out. Chocolate should be wrapped in two layers of protection. For the first layer, either leave the chocolate in the wrapper that the manufacturer provides or wrap the chocolate in a freezer-weight resealable bag and get all of the air out as possible. I like store chocolate in the bags supplied by my home vacuum-sealer and then use the machine to remove the air. The new Press-N-Seal freezer-weight plastic wrap works well, too. Do not use aluminum foil! For the second layer of protection, place the wrapped chocolate inside a resealable heavy-weight freezer bag, making sure you expel all of the air, or use your vacuum-sealer bags and machine. 

If you do freeze your chocolate, make sure it is double-wrapped in freezer-weight bags and fill the container as full as possible to minimize air space. If using a vacuum-sealer, which is preferred, take care not to crush the chocolates. To freeze the chocolate: after wrapping, place the chocolate in the refrigerator for 24 hours prior to freezing to bring its temperature down. If it starts to condense, open the bag and place a paper towel on the chocolate to absorb the moisture. Leave the chocolate there for an hour, remove the towel and rewrap. Immediately place the chocolate in the freezer while the chocolate is still chilled. To thaw, place the frozen block of chocolate in its wrappers in the refrigerator for 24 hours. Then, place the chocolate in a cool place, away from heat or sunlight, to warm to room temperature for 24 hours before using. The process of slowly thawing the chocolate and bringing it to room temperature, helps prevent the formation of condensation on the surface, which in turn will lead to sugar bloom.

Typical problems affecting chocolate:

The basis of chocolate is a delicate emulsion of cocoa solids and cocoa butter. If it is improperly stored or tempered, the emulsion breaks down causing either one or both types of "bloom" to occur -- fat bloom and sugar bloom, a colored film on the outside of the chocolate. Melting and/or tempering bloomed chocolate eliminates the problem, although chocolate affected with sugar bloom should not be melted and used for fine candy making.
bulletSeizing: If moisture in any form comes into contact with the chocolate it will cause it to seize or thicken, rendering it useless for tempering and chocolate work. If not burnt, it can be melted with a small amount of vegetable oil and used for cooking and recipes.
bullet Tempering: If at any time the chocolate is heated beyond the tempering zones, it will burn or a gray "bloom" or white streaks will appear on the outside when cooled. Repeat tempering process.
bulletFat Bloom: The most obvious type of bloom, fat bloom, occurs when the structure of the fat crystals changes during too-warm storage. It looks like gray-white swirls or streaks on the chocolate when it is exposed to heat during storage, usually warmer than 75 degrees F. Storage at a constant, cool temperature is recommended. To keep the chocolate cool, you can freeze it, but then you have to worry about the second type of bloom, called sugar bloom. 
bulletSugar Bloom or Crystallization: occurs when the sugar crystals are affected by moisture. This happens when the chocolate is stored in damp conditions, either from humidity in the air or condensation from refrigeration, causing sugar to dissolve and come to the surface, which leaves it rough. It is visible as white streaks and dots and grainy texture. When the water evaporates afterwards, the sugar on the surface recrystallizes into rough, irregular crystals on the surface. You can prevent sugar bloom by preventing temperature shocks. When chocolate comes out of a cold room, it should be stored in a warm area long enough before opening the package to keep direct condensation from forming.
bulletStripes: The chocolate is not properly mixed during melting or tempering. Stir thoroughly before and during the process. 
bullet Molded chocolates are dull when removed from their mold: The biggest cause is that the chocolate was not tempered properly. The molds were not polished well, or items were left in refrigerator too long after hardening.
bulletWhite marks appear on demolded items: Make sure molds are completely dry before filling. Water can become trapped in molds with heavy patterns.
bullet Molded chocolates crack: If molded items are placed in a refrigerator that is too cold, the chocolate contracts too fast and they will crack.
 Paraffin in chocolate candy:

Paraffin wax, also known as Parawax or Baker's Wax, is widely used on fruits, vegetables, and chocolate candy to make them shiny and pretty and to retard moisture loss and spoilage. Waxes are made from vegetable oils, palm oil derivatives, synthetic resins, as well as other materials. 
I use 1/4 bar (1-ounce) paraffin wax per 1 (12-ounce) package of semisweet chocolate chips.  I use this also when making Christmas candies.  Just melt it with the chocolate in the top of a double boiler over hot water.

Yes, it is edible but not approved by the FDA for consumption. Paraffin wax is often added to chocolate to give a nice, glossy finish and helps it remain solid at room temperature. Be aware that paraffin is flammable when overheated, so warm it gently in a double-boiler only to the point where it is melted.

You can find paraffin wax, in your grocery store where canning jars and supplies are sold because it's commonly used to seal home-canned jellies and jams. However, some paraffin is not intended to be ingested, such as that sold for candle making, so check the label.

 TINT CHOCOLATE:

There isn't a lot written about tinting white chocolate.

You can "paint" colors on the set, molded white chocolate (or any chocolate) or white chocolate plastic -- mix colors by combining powdered food coloring with cocoa butter in a 6 to 1 ratio (cocoa butter to food coloring) and keeping them warm while using them. (A yogurt maker is the perfect temperature range or keeping them in custard cups set on a heating pad set on low, low, low). Add the cocoa butter until you achieve a medium thickness in "paint". Then, paint on your colors using a paintbrush. You can also silkscreen on the colors, if you have time!

However, paste food coloring, as powdered, can be used to color the molded white chocolate or white chocolate plastic with after you mix and refrigerate it for at least an hour. The chocolate plastic has to have the consistency of playdough. Knead the color in.

The best way to tint white chocolate while melting or already melted is with oil based coloring: http://www.kitchenconservatory.com/chocolate.htm But, you can safely use powdered food coloring. Do not use any water-based food coloring or the chocolate will seize and be ruined. Add the color slowly and stir, stir, stir while you do.

You can also use Mercken's Candy Coatings. They come in a myriad of colors and all you do is melt them.

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